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![]() At the anode (positive electrode), negatively charged ions lose electrons and so the reactions are oxidations. During electrolysis, at the cathode (negative electrode), positively charged ions gain electrons and so the reactions are reductions.4.4.3.5 Representation of reactions at electrodes as half equations (HT only).For example, copper can be obtained from solutions of copper compounds by displacement using scrap iron or by electrolysis. The metal compounds can be processed to obtain the metal.4.10.1.4 Alternative methods of extracting metals (HT only).4.10.1 Using the earth's resources and obtaining potable water.Electrolysis of (i) copper sulfate solution with copper electrodes and (ii) acidified water with inert electrodes.(n) electrolysis of aqueous solutions such as copper(II) chloride (including electrode equations).Unit 2: CHEMICAL BONDING, APPLICATION OF CHEMICAL REACTIONS and ORGANIC CHEMISTRY.Conduction in ionic compounds can be explained by the movement of ions towards oppositely charged electrodes.Atomic structure and bonding related to properties of materials.This is to confirm that the mass gained at the cathode is equal to the mass loss at the anode. The electrolysis can be done using two weighed copper strips.the cathode is made of pure copper or a support metal such as stainless steel.the anode consists of an unrefined sample of the metal.This leads to a discussion as to why, during electrolytic refining: Students can then see the copper disappearing from the surface of the copper-coated anode: After doing the electrolysis as described above, the electrodes can be interchanged.Extension experiments for copper refining ![]() It is wise not to complicate electrolytic deposition with chemical displacement – valued articles can be effectively ruined. This happens for instance in items made of metals above copper in the reactivity series. In many cases, an alternative redox reaction often takes place before any current is actually passed. It can be instructive to allow students to copperplate metal objects supplied by the school and previously tested for their suitability. The results of this experiment can lead to a discussion about electroplating and the electrolytic refining of copper. The reaction is the reverse of the cathode reaction. If copper is used for the electrodes, the copper anode dissolves. With carbon (graphite) electrodes, the oxygen usually reacts with the anode to form CO 2. You should explain that, if the current used is much lower, then the solid coating is shiny, impermeable and very difficult to rub off this process forms the basis of electroplating.īubbles of gas (oxygen) are formed at the anode.Ĭathode reaction: Cu 2+(aq) + 2e - → Cu(s)Īnode reaction: 2H 2O(l) → O 2(g) + 4H +(aq) + 4e. Students should see a deposit of copper forming on the cathode. The cathodes can be cleaned using emery paper.Įquipment required for the electrolysis of copper(II) sulfate solution. They should watch for any activity on each of the electrodes, and write down their observations. Ask the students to set up the cell as shown.Copper(II) sulfate solution is HARMFUL if concentration is equal to or greater than 1 M. If the concentrations are increased, the solutions must be labelled with the correct hazard warnings. At the suggested concentrations, the copper(II) sulfate solution is LOW HAZARD. Copper(II) sulfate solution, CuSO 4(aq) – see CLEAPSS Hazcard HC027c and CLEAPSS Recipe Book RB031.Students must wash their hands at the end of all practical work. Read our standard health and safety guidance.Copper strips x2 (optional these can be used in place of the graphite rods as an extension to the basic experiment).Aqueous copper(II) sulfate, about 0.5 M, 200 cm 3.A bulb can be included in the circuit to indicate that there is a flow of current.They can also be fixed using Blutac onto a small strip of wood resting on the top of the beaker. Using a retort stand and clamp is probably the most convenient. There are several ways of securing the graphite electrodes.Light bulb, small, 6 volt, 5 watt (optional note 2).Retort stand and clamp to hold electrodes (note 1).Graphite electrodes, about 5 mm diameter, x2.This class experiment can be done by students working either in pairs or threes. With supporting resources, including illustrated technician notes, integrated instructions, pause-and-think questions, worksheets and more. Use our Electrolysis of aqueous solutions video to support you to deliver this practical lesson. ![]() RSC Yusuf Hamied Inspirational Science Programme. ![]() ![]() ![]() With FT8, activity is limited to a narrow band of frequencies, so it is ideal for use with loop antennas that require retuning when changing frequency, such as CHAMELEON ANTENNA F-Loop 2.0 Portable HF Antenna ( CHA-F-LOOP-2-0). With its popularity, quickly working DXCC or WAS with FT8 is easily within reach of almost any station. This means that even low-powered stations and stations with sub-optimal antennas can make contacts worldwide. ![]() Why would I want toįT8 is designed to maximize communication even when signals are very weak (as low as -24dB). FT8 is one of a group of Multiple Frequency-Shift Keying (MFSK) modes that include JT9, JT65 and MSK144 created by Joe Taylor, K1JT and co-developers. and even older hardware-based modes such as RTTY that we now use our computers to encode and decode. Message into audio tones that are sent out via your sound card to your radio’sįor years there have been a variety of these new software modes including Phase-shift keying (PSK31 & PSK 65), Hellschreiber, Olivia, Pactor, etc. ![]() Conversely, when you want to transmit, the software encodes your Radio to be processed by software to decode the information embedded in the (SCM) because they utilize a computer’s sound card to bring in audio from your Wondering how to get started and why you would want to?įT8 is one of the many digital modes often referred to as sound card modes As one of theįastest growing modes of Amateur Radio it has been hard to miss, but you may be I am guessing that most of you reading this have either heardĪbout FT8 from fellow Hams or heard it on air as that strange repetitiveīuzzing sound between the CW and SSB portions of the bands. ![]() ![]() ![]() Implicit DHCP filter applied when Tunnel All Networks Configured.Firefox Certificate Store on macOS is Not Supported.Interoperability With ISE Posture on macOS.New Split Include Tunnel Behavior (CSCum90946)įailure When Using a SHA512 Certificate for Authentication.An圜onnect Compatibility with Microsoft Windows 10.Windows 10 Defender False Positive─Cisco An圜onnect Adapter Issue.Microsoft Inadvertently Blocks Updates to Windows 10 When Network Access Manager is Installed.Umbrella Roaming Security Module Changes.macOS Keychain Prompts During Authentication.Web Deploy of NAM, DART, ISE Posture, and/or Posture Fails with Signature/File Integrity Verification Error.Network Access Manager Does Not Automatically Fallback to WWAN/3G/4G/5G.Impact on Posture When a Power Event or Network Interruption Occurs.An圜onnect macOS 10.13 (High Sierra) Compatibility.No Hidden Network Scanlist on Network Access Manager with Windows 10 Version 1703 (CSCvg04014).Conflict with Network Access Manager and Group Policy.Changes with Certificate Store Database (NSS Library Updates) on Firefox58.Restored IPsec Connections in FIPS Mode (CSCvm87884).PMK-Based Roaming Not Supported With Network Access Manager. ![]() No Detection of Default Patch Management in ISE Posture (CSCvq64901).macOS Management Tunnel Disconnect After Upgrade to 4.8.GUI Customization on macOS Not Supported.Permission Popups During Initial HostScan or System.HostScan Will Not Function With macOS 10.15 Without Upgrade (CSCvq11813).Windows DNS Client Optimizations Caveat.Nslookup Command Needs macOS Fix To Work As Expected.Potential Issues Connecting to a Wireless Network After An Upgrade from An圜onnect 4.7MR4.Client First Auto-Reconnect Unsuccessful After Upgrading to An圜onnect 4.9.01xxx (Linux Only).Web Deployment Workflow Limitations on Linux.Local and Network Proxy Incompatibilities.An圜onnect 4.10 Upgrade Failure on Linux (Only An圜onnect Versions Prior to 5).Initiating an Automatic VPN Connection With TND (CSCvz02896).Root CA Conflict With Firefox NSS Store (Linux Only).Limitations When Using RPM/DEB Installer.Windows Local Group Policy DNS Settings Ignored.DNS (Name Resolution) on macOS 12.x May Fail.Simultaneous VPN Sessions Not Supported.VPN Headend DNS Load Balancing Not Supported.An圜onnect Support for Microsoft Windows.Secure Firewall ASA Requirements for An圜onnect.Changes to the An圜onnect Profile Editor.An圜onnect HostScan Engine Update 6 New Features.An圜onnect HostScan Engine Update 9 New Features.An圜onnect HostScan Engine Update 4 New Features.An圜onnect HostScan Engine Update 5 New Features.An圜onnect HostScan Engine Update 3 New Features.An圜onnect HostScan Engine Update 0 New Features.An圜onnect HostScan Engine Update 1 New Features.An圜onnect Package Filenames for Predeployment.An圜onnect Secure Mobility Client Package Filenames for Web Deployment.Download the Latest Version of An圜onnect.Release Notes for An圜onnect Secure Mobility Client, Version 4.10. ![]() ![]() ![]() ![]() If you wish to be unblocked, you must agree that you will take immediate steps to rectify this issue. ![]() If you do not understand what is causing this behavior, please contact us here. If you promise to stop (by clicking the Agree button below), we'll unblock your connection for now, but we will immediately re-block it if we detect additional bad behavior. Overusing our search engine with a very large number of searches in a very short amount of time.Using a badly configured (or badly written) browser add-on for blocking content.Running a "scraper" or "downloader" program that either does not identify itself or uses fake headers to elude detection.Using a script or add-on that scans GameFAQs for box and screen images (such as an emulator front-end), while overloading our search engine.There is no official GameFAQs app, and we do not support nor have any contact with the makers of these unofficial apps. Continued use of these apps may cause your IP to be blocked indefinitely. This triggers our anti-spambot measures, which are designed to stop automated systems from flooding the site with traffic. Some unofficial phone apps appear to be using GameFAQs as a back-end, but they do not behave like a real web browser does.Using GameFAQs regularly with these browsers can cause temporary and even permanent IP blocks due to these additional requests. If you are using the Brave browser, or have installed the Ghostery add-on, these programs send extra traffic to our servers for every page on the site that you browse, then send that data back to a third party, essentially spying on your browsing habits.We strongly recommend you stop using this browser until this problem is corrected. The latest version of the Opera browser sends multiple invalid requests to our servers for every page you visit.The most common causes of this issue are: Your IP address has been temporarily blocked due to a large number of HTTP requests. ![]() ![]() ![]() ![]() The pattern element in the name contains the unique identity number of the account or website it relates to. The cookie stores information anonymously and assigns a randomly generated number to recognize unique visitors.Ī variation of the _gat cookie set by Google Analytics and Google Tag Manager to allow website owners to track visitor behaviour and measure site performance. The _ga cookie, installed by Google Analytics, calculates visitor, session and campaign data and also keeps track of site usage for the site's analytics report. These cookies help provide information on metrics the number of visitors, bounce rate, traffic source, etc. It does not store any personal data.Īnalytical cookies are used to understand how visitors interact with the website. The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. The cookie is a session cookies and is deleted when all the browser windows are closed. The cookie is used to store and identify a users' unique session ID for the purpose of managing user session on the website. This cookie is native to PHP applications. It allows the website owner to implement or change the website's content in real-time. This cookie is used by the website's WordPress theme. The cookie is used to store the user consent for the cookies in the category "Performance". This cookie is set by GDPR Cookie Consent plugin. The cookie is used to store the user consent for the cookies in the category "Other. The cookies is used to store the user consent for the cookies in the category "Necessary". ![]() The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". The cookie is used to store the user consent for the cookies in the category "Analytics". Set by the GDPR Cookie Consent plugin, this cookie is used to record the user consent for the cookies in the "Advertisement" category. Stripe sets this cookie cookie to process payments. These cookies ensure basic functionalities and security features of the website, anonymously. Run your project with yarn start.Necessary cookies are absolutely essential for the website to function properly. Interested in doing development on the project?įollow the instructions below and start developing your games right away. Type !commands or !audio to see a list of commands on screen Only users the talk in chat will have their names displayedĪdding the overlay to your stream is super simple!Īdd the following link as you browser source to your streaming software (like OBS): Ĭhange the YOUR_CHANNEL_NAME_HERE in the url to match your channel's name like the following:.All users in your chat get their own sprite.If you would like to fork this repository, you must obtain a license to use sprite assets or replace them with your own. ![]() This project is for refernece and sprite assets have been licensed by me. It's just some simple silly that can be had with out the need of any servers or logging into a website to use. Also doing !audio will display the commands they can use to trigger audio queues that are backed into the overlay. Doing the !controls command will display a dialog on the screen of the various command they can do to controls their sprite. Every person in the chat is reperesented by a sprite on the screen they can control. Twitch Interactive Chat Overlay is a simple and fun overlay to add to your stream that gives chat a new way to interact with you and fellow members of chat. ![]() ![]() ![]() Perry decided to shed her on-stage persona and embrace her self-proclaimed authentic self as Katheryn Hudson, her real name. After releasing Prism (2013) and touring in 2014–2015, Perry went on hiatus to protect her mental health and to return afresh. Prior to the release of the album, Perry had not released new material in four years, with the exception of the 2016 Summer Olympics anthem, " Rise". To promote the album, Perry embarked on her fourth concert tour, Witness: The Tour. The album also topped the charts in Canada and Spain, while reaching number two in Australia, South Korea, Mexico, and New Zealand and the top five region in nine other territories. Moving 180,000 album equivalent units in its first-week, Witness debuted atop the US Billboard 200 chart, becoming Perry's third chart-topping album in the country. Some criticized the production and lyricism, while others welcomed the album's personal nature and singled out certain tracks for praise. Upon release, critics were divided towards the album. To support the album's release, Perry broadcast herself on a four-day YouTube live-stream, titled Katy Perry Live: Witness World Wide. " Save as Draft" and " Hey Hey Hey" were released as subsequent singles on Jand January 12, 2018, respectively, with "Hey Hey Hey" receiving a music video. " Bon Appétit" featuring Migos peaked at number 59, while " Swish Swish" featuring Nicki Minaj reached number 46. Perry described it as an album of "liberation" and "purposeful pop".įive singles aided Witness, out of which, three were released before the album and one reached the top-ten of the Billboard Hot 100 chart: the lead single, " Chained to the Rhythm" featuring Skip Marley, peaked at number four on the Hot 100. Witness is an electropop album that delves into dance and EDM genres, with lyrics on self-empowerment and feminism. For the album, Perry worked with numerous producers, including Jeff Bhasker, Mark Crew, Duke Dumont, Jack Garratt, Oscar Holter, Illangelo, Ilya, Max Martin, Ali Payami and Shellback. It was released on June 9, 2017, by Capitol Records. Witness is the fifth studio album by American singer Katy Perry. ![]() ![]() ![]() It’s also her biggest English-language hit. What was Selena’s biggest English song? “Dreaming of You” - 1995 5410 Leopard Street, Corpus Christi, TX 78408.Music Libraries and Archives in Corpus Christi / Victoria The royal color (how fitting!) was one of Selena’s favorite colors, as was black. Whether it’s a T-shirt, tote bag, vinyl record, or anything else having to do with Selena, chances are, they will all be in purple, with touches of black. In fact, he wrote the smash hit “No Me Queda Más” about his unrequited love for Suzette, who married Billy Arriaga in September, 1993. Ricky then wrote the song No Me Queda Más, about his unrequited love, in 1994 after Suzette’s marriage to Billy Arriaga in September 1993.ĭid Ricky have a crush on Selena? Was Ricky in love with Selena? Ricky actually had feelings for Selena’s sister, Suzette. Who played keyboard for Selena? Ahead of the part 2 premiere, Good Housekeeping talked to the actors and musician Joe Ojeda, who was Selena’s keyboard player, about what the show has meant to them personally.Īs referenced in Selena: The Series, Ricky Vela genuinely did have feelings for Selena’s older sister, Suzette. Was Ricky in love with Selena? Ricky actually had feelings for Selena’s sister, Suzette. (CST) at age 23, 16 days before her 24th birthday, from blood loss and cardiac arrest. How old was Selena when she died? Selena Quintanilla-Pérez was pronounced dead at 1:05 p.m. Hot Latin Songs chart in 1991, the singer’s first number one song. ![]() The track peaked at number one on the U.S. ![]() What was Selena’s first hit song? Selena appeared on “Buenos Amigos” with Salvadoran singer Álvaro Torres. The best Selena Quintanilla songs you need to listen to… Quintanilla Pete Astudillo Selenaīeside this What is one of Selena’s famous songs? Who is the real Ricky Vela? Ricardo “Ricky” Vela is an American musician and songwriter who was the keyboardist for the band Selena y Los Dinos from 1984 to 1995. Selena’s brother and producer of her music, A.B. Vela was angry at this and wrote down his feelings. Why did Ricky Vela cry in Selena? Vela had fallen in love with Selena’s sister, Suzette Quintanilla. In the same way What is Selena’s most famous song? The undisputed Selena classic is “Como la Flor.” With its lovelorn lyrics and a goosebump-inducing vocal and dynamic performance over a pop cumbia beat, this track skyrocketed Selena into superstardom and has become her most famous and representative song. In 2018, they also celebrated their 25th anniversary.“No Me Queda Más” was written by Ricky Vela, and production was handled by Selena’s brother A.B. In 1993, Quintanilla tied the knot with Bill Arriaga, her longtime boyfriend, and in 1998 the couple gave birth to a baby boy whom they named Jovan. She’s also an executive producer for the Netflix series “Selena: The Series.” Quintanilla works for Q-Productions, Inc., her father’s company, and manages the Selena Museum. Numerous albums and songs by the group, such as “Munequito De Trapo,” “Preciosa,” and “Dulce Amor,” to name a few, were also released. The band changed its name to Selena y Los Dinos and gained fame before being offered a record deal by Freddie Records. They performed on the streets, at weddings, and at fairs to help the family financially after being forced to shut down the restaurant. Her sister sang lead vocals, her brother played bass guitar, and she played the drums. Her siblings all acquired this passion from their father. Quintanilla hails from a musical family, and her father, who played in the band Los Dinos, encouraged her enthusiasm and love for music. Quintanilla, a record producer, composer, and songwriter, and her late sister, Selena, a songwriter, model, and fashion designer, among other things. Marcella Samora, her mother, is of Cherokee and Mexican origin. Her father, Abraham Quintanilla, is a film producer, record producer, singer, guitarist, and lyricist. Suzette Michelle Quintanilla was born in Lake Jackson, Texas, on June 29, 1967, to Abraham Quintanilla Jr. ![]() ![]() ![]() Your loan servicer’s identity may be listed in the MERS system. Contact Sente Mortgage Servicing at 51 or 80, or by email at Dial the MERS® Servicer Identification System toll-free at 88 or visit the MERS® website.Find great Austin, TX mortgage lending professionals on Zillow like. Check your monthly mortgage billing statement or payment coupon book Visit Sente Mortgage, Inc.s profile on Zillow to read customer ratings and reviews.One is making your January mortgage payment early, in December. There are several ways to maximize your mortgage interest deduction, but it’s important to know who qualifies for this and the limitations. ![]() To find out who your servicer is you can: Advantages to making your January 2022 mortgage payment in December 2021. If you have questions regarding the servicing of your loan please contact us at 51 or 80, or by email at Sente Mortgage is your loan servicer you can make monthly loan payments and manage your account by registering online here - Sente Servicing. If your loan is transferred to a new servicer, you will receive a notification from your current mortgage servicer and the new servicer. First, your Loan Number, which is a 10-digit number located on your Mortgage Statement or Payment Coupon. You will then be asked to enter 3 pieces of information. To begin, simply click on the word REGISTER located in the middle of the screen. In many cases, the company that provided your loan is not the same company that services your loan. In this video, we want to explain the online account registration process. In today’s market, loans, and the rights to service them, are often bought and sold. Amy Lux is a Loan Processor at Sente Mortgage based in Austin, Texas. Your mortgage servicer handles the day-to-day tasks of managing your loan such as processing your loan payments, responding to borrower inquiries, keeping track of principal and interest paid, and managing your escrow account. Below you’ll find information on the most common product distinctions. In our experience, many borrowers are unaware of the number of loan products and don't know the different types of products and programs that might be available. Please contact our customer support team and they will assist in getting your account unlocked.Once you’ve closed on your home, your loan transitions into the final step of the loan process, servicing. When it comes to selecting a mortgage for your new home purchase, there are a wide array of loan options available. To print an invoice, click on the payment transaction line and then click 'Print ' to open the invoice in a print friendly view. You can also view your account balance within 'Your Account'. The process and timeline for foreclosure varies from state to state. It’s essentially a notice to bring your mortgage current or face foreclosure proceedings. To access and download your invoices, go to 'Invoices and Receipts'. Your lender will likely send another, more serious notice, known as a Demand Letter or Notice to Accelerate. ![]() You’ll need to use your registered email address to access invoices. You will be be sent an email with instructions on how to set your password. If it’s your first time logging in, click ‘sign up’ and enter your name and email. An Adjustable Rate Mortgage (commonly referred to as an ARM), is a home loan that the interest payment changes, or adjusts, over the life of the loan. Your browser is out of date and not supported by this application, in order to use this application, please update your browser to the. You will be prompted to log in using your registered email (this is the email you gave us when you first signed up). Visit the Billing Portal by clicking the link above. Our Billing Portal lets you view and pay your Paymentsense invoices at any time. Each month, you’ll be notified via e-mail when a new invoice is uploaded into your billing portal. ![]() ![]() In this process, the female produces a single egg and three other products known as polar bodies, which she usually absorbs. Sharks are a rare example of asexual reproduction, with automic parthenogenesis being the process by which parts of the human body become electrically energized. ![]() Asexual Reproduction In Sharks: An Evolutionary Adaptation Even without the use of traditional sexual reproduction methods, organisms can thrive and make a name for themselves. Nature’s ability to adapt to changing environments and thrive is a testament to its remarkable capabilities, as well as the wide range of options it has for species to adapt to new environments. The Amazon molly genome has recently been sequenced and scientists were surprised to discover that it is thriving despite the genetic disadvantages that come with asexual reproduction. Amazon molly, on the other hand, is asexually reproducing fish that can reproduce without a partner. ![]() Male sharks have claspers on their pelvic fins that allow them to transfer sperm to female sharks. The Amazon Molly exemplifies the complex and diverse nature of life in the natural world. Bubbles, despite being exposed to three mature male breeding males, chose parthenogenesis at the very least. Zebra sharks can reproduce asexually, but this is extremely rare. Despite this, the majority of reports have been from females who have never had a boyfriend. Some of these animals include sharks, turtles, Komodo dragons, snakes, and rays. Previously, it was believed that sharks only reproduced sexually.ĭespite their normal sexual reproduction, some vertebrate species can produce eggs without becoming sexually active. By understanding the reproductive process of the zebra shark, we can better appreciate the importance of protecting this species in the wild.įemale hammerhead sharks, according to a team of international researchers, can reproduce without males by parthenogenesis, or virgin birth.Īccording to a study conducted by researchers from nine countries, female hammerhead sharks can reproduce without males by parthenogenesis, or virgin birth. We will also discuss the importance of conservation efforts for this species and the potential threats that they face. ![]() But how exactly do these sharks reproduce? This article aims to answer this question by delving into the mating habits, mating ritual and reproductive cycle of zebra sharks, as well as outlining the role that males and females play in the process. Zebra sharks boast a unique, spotty pattern on their skin and have become popular in aquariums due to their attractive appearance. Zebra sharks, (Stegostoma fasciatum), are an enigmatic species found in the tropical and subtropical waters of the Indian and Pacific Oceans. ![]() |
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